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Chemiluminescence in Analytical Chemistry - download pdf or read online

By Ana M. Garcia-Campana

ISBN-10: 0585405417

ISBN-13: 9780585405414

ISBN-10: 0824704649

ISBN-13: 9780824704643

Discusses static recommendations and flowing circulation measurements of chemiluminscence utilized to chemical research, with studies of advances in immunoassay innovations and makes use of of enzyme reactions. contains attention of various functions in analytical study, biotechnology and chemical qc.

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Extra resources for Chemiluminescence in Analytical Chemistry

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R Bernard. La Luminescence. Paris: Presse Universitaire de France, 1961, pp 9–11. A Jablonski. Z Physik 94:38–46, 53–65, 1935. GN Lewis, M Kasha. J Am Chem Soc 66:2100, 1944. GN Lewis, M Kasha. J Am Chem Soc 67:1332, 1945. M Kasha. Chem Rev 41:401, 1947. DS McClure. J Chem Phys 17:905, 1949. MC Goldberg, ER Wedner. In: MC Goldberg, ed. Luminescence Application in Biological, Chemical, Environmental and Hydrological Sciences. Washington, DC: American Chemical Society, 1989, chapter 1, p 6. GN Lewis, D Lipkin, TT Magel.

In: M De Luca, ed. Methods in Enzymology. New York: Academic Press, 1978, p. 3. G Wettermark, H Stymne, SE Brolin, B Peterson. Anal Biochem 63:293, 1975. A Lundin. In: LJ Kricka, TJN Carter, ed. Clinical and Biochemical Luminescence. New York: Marcel Dekker, 1982, pp 43–74. HR Schroeder, PO Vogelhut, RJ Carrico, RT Buckler. Anal Chem 48:1933–1937, 1976. I Weeks, I Beheshti, F McCapra, AK Campbell, JS Woodhead. Clin Chem 29: 1474–1479, 1983. I Weeks, JS Woodhead. Clin Chim Acta 141:275–280, 1984.

To predict whether the CL reaction will occur or not, it is possible to use the free energy (∆G): ∆G ϭ ∆H Ϫ T∆S (1) where T is temperature, ∆H is enthalpy, and ∆S is entropy. Enthalpy is the actual energy source for generating the electronically excited state product. To initiate the chemical reaction the activation energy (∆H A) is absorbed. The available energy to produce the excited state (∆E EX ) must be the difference between the reaction energy and the activation energy. mol Ϫ1). 86. 10 4 ϭ λ ex λ ex (3) Garcı´a-Campan˜a et al.

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Chemiluminescence in Analytical Chemistry by Ana M. Garcia-Campana

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