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Helena Dodziuk's Cyclodextrins and Their Complexes: Chemistry, Analytical PDF

By Helena Dodziuk

ISBN-10: 3527312803

ISBN-13: 9783527312801

ISBN-10: 3527608982

ISBN-13: 9783527608980

Providing complete and updated knowledge in a single compact ebook, an skilled editor and most sensible authors hide each element of those very important molecules from molecular acceptance to cyclodextrins as enzyme models.

Chapters contain reactivity and chemistry, chromatography, X-ray, NMR plus different physicochemical tools, in addition to version calculations, rotaxane and catenane constructions, and functions within the pharmaceutical undefined. The publication additionally discusses different purposes resembling within the cosmetics, toiletries, fabric and wrapping industries, agrochemistry, electrochemical sensors, and devices.

A needs to for everybody operating with those components.

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Additional info for Cyclodextrins and Their Complexes: Chemistry, Analytical Methods, Applications

Sample text

J. Am. Chem. Soc. 1988, 110, 4379–4391. 135 Armstrong, D. ; Han, S. ; Menges, R. A. Anal. Chem. 1987, 2594. ; Sybilska, D. J. Chromat. 2000, 902, 381. ; Sybilska, D. Pol. J. Chem. 1996, 70, 1361. ; Perez, G. J. Chromatogr. A 2003, 1010, 233. 1 Scope of This Chapter The classic chemistry of native CyDs is now a kind of completed area, described in a book [1] and several reviews that summarize state-of-the-art syntheses of these macrocycles [2–4], while syntheses of several novel CyD structures or their analogues are given in the literature [5–8].

Carofiglio T, Cordioli M, Fornasier R, Jicsinsky L, Tonellato U, Carbohydr. Res. 2004, 339, 1361– 1366. Leung DK, Atkins JH, Breslow R, Tetrahedron Lett. 2001, 42, 6255–6258. Aoki N, Arai R, Hattori K, J. Inclusion Phenom. 2004, 50, 115–120. Nelissen HFM, Feiters MC, Nolte RJM, J. Org. Chem. 2002, 67, 5901– 5906. Garcia-Ruiz C, Crego AL, Marina ML, Electrophoresis 2003, 24, 2657– 2664. Baussanne I, Benito JM, Mellet CO, Garcia-Fernandez JM, Law H, Defaye J, Chem. Commun. 2000, 1489–1490. Yamanoi T, Yoshida N, Oda Y, Akaike E, Tsumida M, Kobayashi N, Osumi K, Yamamoto K, Fujita K, Takahashi K, Hattori K, Bioorg.

The a- and g-CyD analogues, which possess a hexa-2,5-diyne-1,6-dioxy unit, were synthesized by intramolecular coupling of bis-O-propargylated maltohexaoside or the analogous maltooctaoside [121]. All the glycosilation for chain elongation and cyclization of saccharides was carried out after tethering the donor to the acceptor by a phthaloyl bridge to give the desired saccharides in good yields [122]. 3 Chemistry of Modified Cyclodextrins Various modified CyDs have been prepared to improve their binding affinities and selectivities controlled by external factors such as photons, metal ions, or pH.

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Cyclodextrins and Their Complexes: Chemistry, Analytical Methods, Applications by Helena Dodziuk


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